RUTHENIUM(II) - CATALYZED OXIDATION OF ALCOHOLS BY PERSULFATE

被引：12

作者：

BRESSAN, M

FORTI, L

GHELFI, F

MORVILLO, A

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM ORGAN,VIA MARZOLO 1,I-35131 PADUA,ITALY

[2] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 79卷 / 1-3期

关键词：

ALCOHOLS; OXIDATION; PERSULFATE; RUTHENIUM;

D O I：

10.1016/0304-5102(93)85093-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alcohols are oxidized to carbonylic compounds by aqueous persulfate in the presence of catalytic amounts (0.2%) of ruthenium trichloride and of a choice of ruthenium(II) complexes. Secondary alcohols are quantitatively converted to ketones, whereas primary alcohols can be converted to aldehydes with good selectivities. A kinetic investigation suggests a concerted mechanism for the bi-electronic oxygen transfer.

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页码：85 / 93

页数：9

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