SYNTHESIS AND CHARACTERIZATION OF ACTIVATED PITCH-BASED CARBON-FIBERS

被引:13
作者
THWAITES, MW [1 ]
STEWART, ML [1 ]
MCNEESE, BE [1 ]
SUMNER, MB [1 ]
机构
[1] ASHLAND CARBON FIBERS DIV,ASHLAND,KY 41114
关键词
D O I
10.1016/0378-3820(93)90096-M
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Recently there has been an increase in interest in the production, properties and applications of activated carbon fibers (ACF) produced from pitch precursors. These fibers offer a number of advantages and because of their novel properties may be more suitable in certain applications than conventional granular and powdered activated carbons. The isotropic nature of pitch-based fibers makes it possible to create high specific surface areas in the region of 700-2000 m2/g; because diffusion limitations are minimal, the fibers exhibit very high rates of adsorption and desorption, and they may be produced in a wide variety of woven and non-woven forms. The adsorptive properties of these fibers are not as well-studied as those of other commercial activated carbons. This paper describes the synthesis and pore structure characterization of activated Ashland petroleum pitch carbon fibers, by gas adsorption and mercury porosimetry.
引用
收藏
页码:137 / 145
页数:9
相关论文
共 12 条
[1]  
BERKEBILE DC, 1991, Patent No. 4996037
[2]  
BOTHA FD, 1992, COMMUNICATION
[3]   OBSERVATIONS CONCERNING DETERMINATION OF POROSITIES IN GRAPHITES [J].
DICKINSON, JM ;
SHORE, JW .
CARBON, 1968, 6 (06) :937-+
[4]   HOMOGENEOUS AND HETEROGENEOUS MICROPORE STRUCTURES IN CARBONACEOUS ADSORBENTS [J].
DUBININ, MM ;
STOECKLI, HF .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1980, 75 (01) :34-42
[5]  
GREGG SJ, 1982, ADSORPTION SURFACE
[6]   MICROPOROSITY AND ADSORPTION CHARACTERISTICS AGAINST NO, SO2, AND NH3 OF PITCH-BASED ACTIVATED CARBON-FIBERS [J].
KANEKO, K ;
NAKAHIGASHI, Y ;
NAGATA, K .
CARBON, 1988, 26 (03) :327-332
[7]  
LEE DW, 1989, HWAHAK KONGHAK, V27, P777
[8]   EVALUATION OF THE MICROPOROSITY IN ACTIVATED CARBONS BY N-NONANE PREADSORPTION [J].
RODRIGUEZREINOSO, F ;
MARTINMARTINEZ, JM ;
MOLINASABIO, M ;
TORREGROSA, R ;
GARRIDOSEGOVIA, J .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1985, 106 (02) :315-323
[9]  
RYU SK, 1990, CARB 90 PAR, P96
[10]  
Ryu SK., 1990, HIGH TEMP-HIGH PRESS, V22, P345