SHOCK-INITIATED EXOTHERMIC REACTIONS .V. OXIDATION OF ETHYLENE

被引：13

作者：

DRUMMOND, LJ

机构：

[1] Australian Defence Scientific Service, Weapons Research Establishment, Salisbury, SA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1968年 / 21卷 / 11期

关键词：

D O I：

10.1071/CH9682641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mixtures of C2H4 with 02 or N3O and argon have been ignited with reflected shocks. The temperature dependence of the induction period to explosion suggests that the rate-controlling reaction for the C2H4-02 system is CH2O + O2 + CHO +HO2. Results for the C2H4-N2O system do not identify one particular reaction as being rate-controlling. A combination of reactions is probably involved. Possibilities include the pyrolysis of ethylene and of ethylene oxide and the reaction CH2+N2O CH+OH+N2. © 1968 CSIRO. All rights reserved.

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页码：2641 / &

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