ASPECTS OF AROMATIC IRON SANDWICHES - APPLICATION TO ORGANIC AND ORGANOMETALLIC SYNTHESIS

被引:16
作者
ASTRUC, D [1 ]
HAMON, JR [1 ]
MANDON, D [1 ]
MOULINES, F [1 ]
机构
[1] LAB CHIM ORGANOMET,CNRS,URA 347,F-35042 RENNES,FRANCE
关键词
D O I
10.1351/pac199062061165
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of nucleophiles with [FeII (n5-cyclohexadienyl)(n6-C6H6)]+ givesubstituted cyclohexadiene FeU complexes which, on treatment with Ph3C+ produce substituted cyclohexadienyl complexes which can then undergo reaction with a second nucleophile. Reaction of [FeCp(C6(CHo)fi)]+ with t-BuOK and alkyl halides RX gives [FeCp(C6(CH2R)6)]. +. © 1990 IUPAC
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页码:1165 / 1168
页数:4
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