THERMAL-PROPERTIES OF THIOCYANATOTHIOCARBAMIDOBISMUTHATES(III) WITH ALKALINE ELEMENTS

被引：11

作者：

LADZINSKAKULINSKA, H

机构：

[1] Institute of General Chemistry, University of Technology, Lódź

来源：

THERMOCHIMICA ACTA | 1979年 / 33卷 / OCT期

关键词：

D O I：

10.1016/0040-6031(79)87053-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The thermal decomposition of complex salts of thiocyanatothiocarbamidobismuthates(III), having the general formula Me[Bi(SCN)4(TM)2] where Me = Li, Na, K, Rb, Cs, NH4 and TM = thiourea, was studied. On the basis of the results of derivatographic studies and chemical analysis, both infrared spectrophotometric and diffractometric, the compositions of the intermediate and final products obtained during the thermal decomposition of those salts were established. On the strength of the experimental data obtained (without analyzing the gaseous products), the most probable overall equation was established of the decomposition reaction of thiocyanatothiocarbamidobismuthates(III) in air at a temperature of 480°C. © 1979.

引用

页码：293 / 300

页数：8

共 8 条

[1]

BORISOWA G, 1975, ZH NEORG KHIM, V22, P1806

[2]

CYGANSKI A, 1976, ROCZ CHEM, V50, P391

[3]

DOLLIMORE D, 1970, DIFFERENTIAL THERMAL, P427

[4] *DIE VERWENDUNG VON THIOACETAMID IN DER QUANTITATIVEN ANALYSE .1. DIE BESTIMMUNG DES ANTIMONS [J].