RAMAN AND INFRARED STUDIES OF CUPRIC OXIDE

被引：30

作者：

GUHA, S

PEEBLES, D

WIETING, JT

机构：

[1] U.S. Naval Research Laboratory, Washington D.C., 20375-5000

[2] SFA Inc., Landover, Maryland

来源：

BULLETIN OF MATERIALS SCIENCE | 1991年 / 14卷 / 03期

关键词：

RAMAN; INFRARED; CUPRIC OXIDE;

D O I：

10.1007/BF02744682

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Polarized Raman and fourier-transform infrared (FTIR) measurements have been made on a single crystal of CuO. Group theory predicts nine vibrations of which three (A(g), 2B(g)) are Raman-active and six (3A(u), 3B(u)) are infrared-active. We have observed three Raman modes at 296 (A(g)), 346 (B(g)1) and 636 (B(g)2) cm-1. We have also observed six infrared modes at 146 (B(u)3), 164 (A(u)2), 355 (A(u)3), 480 (B(u)1), 542 (?) and 603 (B(u)2) cm-1. The normal frequencies and eigenvectors have been calculated using Wilson's FG method; a good fit between theory and experiment has been obtained.

引用

页码：539 / 543

页数：5

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