METAL-COMPLEXES WITH BIOLOGICALLY-ACTIVE LIGANDS .59. SYNTHESIS AND STRUCTURE OF CHIRAL CHLORO(DIMETHYLSULFOXIDE) (ETA-5-PENTAMETHYLCYCLOPENTADIENYL)THYMINATOIRIDIUM(III)

被引：14

作者：

KRAMER, R ^{[1
]}

POLBORN, K ^{[1
]}

BECK, W ^{[1
]}

机构：

[1] UNIV MUNICH, INST ANORGAN CHEM, MEISERSTR 1, W-8000 MUNICH 2, GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 410卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)83029-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chloro-bridged complex [Cp*IrCl2]2 reacts with thyminate in the presence of dimethylsulfoxide to give the chiral complex Me2(O)S(Cp*)(Cl)Ir(thyminate). X-ray diffraction shows N1-bound thyminate and S-coordinated DMSO in the crystal which contains both S(Ir) and R(Ir) enantiomers.

引用

页码：111 / 116

页数：6

共 26 条

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