CATALYTIC AMINOMERCURATION OF OLEFINS IN A TANDEM AMINOMERCURATION-DEOXYMERCURATION - ONE-STEP SYNTHESIS OF SECONDARY N-ARYLALLYLAMINES FROM ALLYLALCOHOLS

被引:8
作者
BARLUENGA, J
PEREZPRIETO, J
ASENSIO, G
机构
[1] UNIV VALENCIA,FAC FARM,DEPT QUIM ORGAN,AVDA BLASCO IBANEZ 13,E-46010 VALENCIA,SPAIN
[2] UNIV OVIEDO,FAC QUIM,DEPT QUIM ORGANOMETAL,E-33006 OVIEDO,SPAIN
关键词
D O I
10.1016/S0040-4020(01)82026-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Allyl alcohols react with primary aromatic amines and stoichiometric amounts of mercury(II) tetrafluoroborate to give mixtures of mono- and diallyl anilines. However, the use of the tandem aminomercuration-deoxymercuration promoted by catalytic mercury(II) tetrafluoroborate allows to perform regiospecifically the monoallylation reaction with very high yields. A mechanism is proposed to account for the observed results. © 1990.
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页码:2453 / 2460
页数:8
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