QUINONE-AMINE-REACTIONS .1. REACTIONS BETWEEN 2-METHYL-1,4-NAPHTHOQUINONE AND 4-AMINOPHENOL

被引：12

作者：

KALLMAYER, HJ

机构：

[1] Institut für Pharmazie und Lebensmittelchemie, Universität Würzburg, Würzburg, 8700, Am Hubland

来源：

ARCHIV DER PHARMAZIE | 1979年 / 312卷 / 03期

关键词：

D O I：

10.1002/ardp.19793120309

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

2‐Methyl‐1,4‐naphthochinon (1) reagiert mit 4‐Aminophenol zu 2‐Methyl‐1,4‐naphthochinon‐4‐(N‐4′‐hydroxyphenyl)‐imin (6), 2‐Methyl‐3‐(4′‐hydroxyphenyl)amino‐1,4‐naphthochinon (7) und 2‐(N‐4′‐Hydroxyphenyl)‐aminomethyl‐1,4‐naphthochinon (8) (MS, 1H‐NMR, IR, UV/S). Tautomere der Reaktionsprodukte werden diskutiert. Die Farbe von 8 wird auf intramolekulare CT‐Wechselwirkung zwischen Chinon‐ und Anilinteil des Moleküls zurückgeführt. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：230 / 239

页数：10

共 32 条

[1] COLOURING MATTERS OF APHIDIDOE .18. STRUCTURE + CHEMISTRY OF ERYTHROAPHINS
CAMERON, DW
CROMARTIE, RIT
HAMIED, YK
TODD
SCOTT, PM
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JAN): : 62 - &
[2] SIDE-CHAIN AMINATION - NEW REACTION OF NUCLEARALKYLATED QUINONES
CAMERON, DW
TODD
SCOTT, PM
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JAN): : 42 - &
[3] SIDE-CHAIN VERSUS NUCLEAR AMINATION OF METHYL-SUBSTITUTED BENZO- AND NAPHTHO-QUINONES
CAMERON, DW
GILES, RGF
TITMAN, RB
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1969, (09): : 1245 - +
[4] CAMERON DW, 1964, J CHEM SOC, P5569
[5] INTRAMOLECULAR DONOR-ACCEPTOR INTERACTION BETWEEN AROMATIC AMINES AND QUINONES
CARRUTHERS, R
DEAN, FM
HOUGHTON, LE
LEDWITH, A
[J]. CHEMICAL COMMUNICATIONS, 1967, (23) : 1206 - +
[6] HYDROGEN ISOTOPE EXCHANGE IN METHYL-QUINONES
CLARK, VM
HUTCHINS.DW
WILSON, RG
[J]. CHEMICAL COMMUNICATIONS, 1968, (01) : 52 - &
[7] DAHNE S, 1966, ANGEW CHEM, V78, P1029
[8] ADDUCTS FROM QUINONES AND DIAZOALKANES .6. FORMATION OF A XANTHEN DERIVATIVE RELATED TO DIDUROQUINONE
DEAN, FM
HOUGHTON, LE
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1968, (16): : 2060 - &
[9] ADDUCTS FROM QUINONES AND DIAZOALKANES .7. FUNCTION OF QUINONE METHIDES IN SIDE-CHAIN AMINATION OF ALKYLQUINONES AND IN DIMERISATIONS GIVING ETHYLENEDIQUINONES
DEAN, FM
HOUGHTON, LE
MORTON, RB
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1968, (16): : 2065 - &
[10] DETSINA AM, 1977, ZH ORG KHIM+, V13, P224

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