OXIDATION OF ACETYLENES WITH TERT-BUTYL HYDROPEROXIDE CATALYZED BY SELENIUM DIOXIDE - ALPHA,ALPHA'-DIOXYGENATION OF INTERNAL ALKYNES

被引：44

作者：

CHABAUD, B ^{[1
]}

SHARPLESS, KB ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 23期

关键词：

D O I：

10.1021/jo01337a045

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unlike olefins, acetylenes show a strong tendency to undergo α, α&-dioxygenation upon reaction with Se02. The oxidation of ten different acetylenes allowed assignment of the reactivity sequence: CH2≃CH > CH3. Alkynes bearing one methylene and one methine substituent afforded the enynone as the major product. © 1979, American Chemical Society. All rights reserved.

引用

页码：4202 / 4204

页数：3

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