A THIOXANONE-BASED CHIRAL TEMPLATE - ASYMMETRIC INDUCTION IN THE [2,3]-SIGMATROPIC REARRANGEMENT OF SULFUR YLIDS - ENANTIOSELECTIVE PREPARATION OF C-BETA-CHIRAL PENT-4-ENOIC ACIDS

被引：35

作者：

KURTH, MJ

TAHIR, SH

OLMSTEAD, MM

机构：

[1] Department of Chemistry, University of California, Davis

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 08期

关键词：

D O I：

10.1021/jo00295a010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A thioxanone-based [2,3]-sigmatropic rearrangement strategy which delivers Cβ-chiral pent-4-enoic acids with excellent Cβ-induction is reported. © 1990, American Chemical Society. All rights reserved.

引用

收藏

页码：2286 / 2288

页数：3

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