THE TITANIUM(IV) COMPLEX OF A HEXADENTATE TRICATECHOL LIGAND - SYNTHESIS, CRYSTAL-STRUCTURE AND ELECTROCHEMISTRY

被引：30

作者：

HAHN, FE ^{[1
]}

RUPPRECHT, S ^{[1
]}

MOOCK, KH ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST ANORGAN & ANALYT CHEM,W-1000 BERLIN 33,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/c39910000224

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tricatechol ligand, tripace, forms an octahedral complex with Ti(iv); the complex possesses a protonated central nitrogen atom in the 'in' conformation and is stable towards reduction up to E1/2 = -1.02 V vs. standard calomel electrode.

引用

页码：224 / 225

页数：2

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