LIPASE-CATALYZED OPTICAL RESOLUTION OF 2,2,2-TRIFLUORO-1-(1-NAPHTHYL)ETHANOL

被引：7

作者：

KATO, K

KATAYAMA, M

GAUTAM, RK

FUJII, S

KIMOTO, H

机构：

[1] Department of Chemistry, National Industrial Research Institute of Nagoya, Nagoya, Hirate-cho

来源：

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1994年 / 58卷 / 07期

关键词：

D O I：

10.1271/bbb.58.1353

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The optical resolution of the title compound (TFNE) was achieved by lipase LIP-catalyzed enantioselective acetylation (E value > 100) with vinyl acetate in octane. S-TFNE acetate and R-TFNE were obtained with high optical purity.

引用

页码：1353 / 1354

页数：2

共 14 条

[1] PREPARATION AND PROPERTIES OF CHIRAL FLUOROORGANIC COMPOUNDS [J].

BRAVO, P ;

RESNATI, G .

TETRAHEDRON-ASYMMETRY, 1990, 1 (10) :661-692

[2]

BUCCIARELLI M, 1983, SYNTHESIS-STUTTGART, P897

[3] QUANTITATIVE-ANALYSES OF BIOCHEMICAL KINETIC RESOLUTIONS OF ENANTIOMERS [J].

CHEN, CS ;

FUJIMOTO, Y ;

GIRDAUKAS, G ;

SIH, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (25) :7294-7299

[4] ENANTIOSELECTIVE REDUCTION OF ARYL TRIFLUOROMETHYL KETONES WITH BINAL-H - PREPARATION OF 2,2,2-TRIFLUORO-1-(9-ANTHRYL)ETHANOL [J].

CHONG, JM ;

MAR, EK .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (02) :893-896

[5] ASYMMETRIC SYNTHESIS AT NITROGEN BY OXIDATION OF IMINES WITH META-CHLOROPEROXYBENZOIC ACID IN PRESENCE OF OPTICALLY-ACTIVE ALCOHOLS [J].

FORNI, A ;

MORETTI, I ;

TORRE, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (20) :731-732

[6] ENZYMATIC PREPARATION OF BOTH ENANTIOMERS OF 4,4,4-TRIFLUORO-3-(INDOLE-3-)BUTYRIC ACID, A NOVEL PLANT-GROWTH REGULATOR [J].

KATO, K ;

KATAYAMA, M ;

GAUTAM, RK ;

FUJII, S ;

KIMOTO, H .

JOURNAL OF FERMENTATION AND BIOENGINEERING, 1993, 76 (03) :178-183

[7]

KATO K, 1993, DEC ANN M SOC FERM B, P120

[8] CHEMICAL INACTIVATION OF LIPASE IN ORGANIC-SOLVENT - A LIPASE FROM PSEUDOMONAS-AERUGINOSA TE3285 IS MORE LIKE A TYPICAL SERINE ENZYME IN AN ORGANIC-SOLVENT THAN IN AQUEOUS-MEDIA [J].

NAKATANI, T ;

HIRATAKE, J ;

YOSHIKAWA, K ;

NISHIOKA, T ;

ODA, J .

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY, 1992, 56 (07) :1118-1123

[9] NONEQUIVALENCE OF NUCLEAR MAGNETIC RESONANCE SPECTRA OF ENANTIOMERS IN OPTICALLY ACTIVE SOLVENTS .4. ASSIGNMENT OF ABSOLUTE CONFIGURATION [J].

PIRKLE, WH ;

BEARE, SD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (21) :5485-&

[10] EXAMPLE OF AUTOMATED LIQUID-CHROMATOGRAPHY - SYNTHESIS OF A BROAD-SPECTRUM RESOLVING AGENT AND RESOLUTION OF 1-(1-NAPHTHYL)-2,2,2-TRIFLUOROETHANOL [J].

PIRKLE, WH ;

HOEKSTRA, MS .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (26) :3904-3906

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