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STUDIES OF BORANES .24. SOME CHEMISTRY OF OCTABORANE-12 AND PREPARATION OF OCTABORANE-14

被引：37
作者：
DOBSON, J
SCHAEFFE.R
机构：
[1] Department of Chemistry, Indiana University, Bloomington
来源：
INORGANIC CHEMISTRY | 1968年 / 7卷 / 03期
关键词：
D O I：
10.1021/ic50061a002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Octaborane-12 has been found to be a strong monobasic Lewis acid; several compounds of the type B8H12·L were prepared. Octaborane-12 was nearly quantitatively converted to hexaborane-10 by limited hydrolysis and in about 45% yield to n-nonaborane-15 by diborane. A new octaborane, octaborane-14, was prepared from octaborane-12 in a two-step conversion. © 1968, American Chemical Society. All rights reserved.
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页码：402 / &
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