STRUCTURE AND REACTIVITY OF HIGHLY SUBSTITUTED CYCLOBUTYL TOSYLATES

被引:2
作者
DOLBY, LJ
WILKINS, CL
机构
[1] Department of Chemistry, University of Oregon, Eugene
关键词
D O I
10.1016/S0040-4020(01)82786-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The solvolyses, in 80% aqueous ethanol, of cis- and trans-3-hydroxy-2,2-4,4-tetramethylcyclobutyl tosylates and of cis- and trans-3-hydroxy-2,2,3,4,4-pentamethylcyclobutyl tosylates have been studied. The observed rate differences are explained in terms of steric effects on the transition states for the reactions. © 1969.
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页码:2381 / &
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