UNIQUE ALDEHYDE CHEMILUMINESCENCE INVOLVING PEROXIDE AND COPPER-I IN ACIDIC DMSO

被引：4

作者：

RUDIE, NG

WAMPLER, JE

机构：

[1] Bioluminescence Laboratory, Department of Biochemistry, University of Georgia, Athens, Georgia

来源：

PHOTOCHEMISTRY AND PHOTOBIOLOGY | 1979年 / 29卷 / 01期

关键词：

D O I：

10.1111/j.1751-1097.1979.tb09277.x

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Simple aliphatic aldehydes, when mixed with hydrogen peroxide in acidic, aprotic solvents containing copper I, chemiluminesce weakly. The reaction is very specific for copper I. Quantum yield determinations reveal a catalytic role for copper I and a 1:1 stoichiometry for aldehyde and hydrogen peroxide. Kinetics reveal that an aldehyde/peroxide adduct is the active compound and synthetic l‐hydroxy octyl hydroperoxide is completely active in the reaction. Similarities in substrates. kinetics and insensitivity to extraneous substances suggest this reaction as a model for earthworm bioluminescence. Copyright © 1979, Wiley Blackwell. All rights reserved

引用

页码：171 / 174

页数：4

共 24 条

[1] INFLUENCE OF SOLVENT ON STABILITY OF METAL-ION COMPLEXES [J].