14 ELECTRON MONOALKYL AND MONOHYDRIDO DERIVATIVES OF CYCLOOCTATETRAENEZIRCONIUM - REDUCTION OF CARBON-MONOXIDE TO FORMALDEHYDE

被引：19

作者：

BERNO, P ^{[1
]}

FLORIANI, C ^{[1
]}

CHIESIVILLA, A ^{[1
]}

GUASTINI, C ^{[1
]}

机构：

[1] UNIV PARMA,CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,IST STRUTTURIST CHIM,I-43100 PARMA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 02期

关键词：

D O I：

10.1039/c39910000109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Zr(eta-8-C8H8)(OAr)(Cl)] (Ar = 2,6-Bu(t)2-C6H3) 2 was transformed into the corresponding methyl, [Zr(eta-8-C8H8)(Me)(OAr)] 3 and dimeric hydrido, [{Zr(eta-8-C8H8)(OAr)}2(mu-H)2] 4 derivatives; the latter complex reduced CO to formaldehyde to produce the dimeric [{Zr(eta-8-C8H8)(OAr)}2(mu-CH2O)] 5, isostructural to 4.

引用

页码：109 / 110

页数：2

共 22 条

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