NOVEL ETA(3)-CYCLOPENTENOYL COMPLEXES OF RUTHENIUM(IV) - X-RAY STRUCTURES OF RU(ETA(5)-C5H5)(ETA(3)-C5H4OBR)BR2 AND RU(ETA(5)-C5H5)(ETA(3)-C5H5O)BR2

被引：13

作者：

KIRCHNER, K ^{[1
]}

MEREITER, K ^{[1
]}

SCHMID, R ^{[1
]}

机构：

[1] TECH UNIV VIENNA,INST MINERAL CRYSTALLOG & STRUCT CHEM,A-1060 VIENNA,AUSTRIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 02期

关键词：

D O I：

10.1039/c39940000161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ru(eta(5)-C5H5)(eta(4)-C5H4O)Br 1 reacts with Br-2 to yield the novel eta(3)-allyl complex Ru(eta(5)-C5H5)(eta(3)-C5H4OBr)Br-2 3; treatment of Ru(eta(5)-C5H5)(eta(4)-C8H12)Br 5 with 3-bromo-4-cyclopentene-l-one gives:the parent cyclopentenoyl complex Ru(eta(5)-C5H5)(eta(3)-C5H5O)Br-2 6, which in the presence of NEt(3) is readily converted to the cyclopentadienone complex 1; X-ray Structures of 3 and 6 are presented.

引用

页码：161 / 162

页数：2

共 9 条

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