MOLECULAR ENGINEERING OF CYANINE-TYPE FLUORESCENT AND LASER-DYES

被引:74
作者
CZERNEY, P [1 ]
GRANESS, G [1 ]
BIRCKNER, E [1 ]
VOLLMER, F [1 ]
RETTIG, W [1 ]
机构
[1] HUMBOLDT UNIV BERLIN,W NERNST INST PHYS & THEORET CHEM,D-10117 BERLIN,GERMANY
关键词
CYANINE DYES; FLUORESCENCE PROPERTIES; LASING EFFICIENCY;
D O I
10.1016/1010-6030(94)04018-W
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The absorption and emission characteristics of several bis(dialkylamino)benzopyrylium dyes are compared, and their very different fluorescence quantum yields are correlated with the calculated energies of the lowest excited states of twisted cyanine dyes. The latter are models for selectively bridged compounds. The laser performance of the dyes is described and compared with well-known laser dyes. The 4-(2-carboxyphenyl)-substituted pyrylium salts are considerably more stable than the unsubstituted compounds.
引用
收藏
页码:31 / 36
页数:6
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