REACTIONS OF PRIMARY ALKYLANTIMONY COMPOUNDS - FORMATION OF THE MACROMOLECULAR SPECIES (RSB)X AND (RSBI0.4)X

被引：8

作者：

CHOUDHURY, P ^{[1
]}

ELSHAZLY, MF ^{[1
]}

SPRING, C ^{[1
]}

RHEINGOLD, AL ^{[1
]}

机构：

[1] SUNY COLL PLATTSBURGH,DEPT CHEM,PLATTSBURGH,NY 12901

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1021/ic50193a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the primary alkylstibines CH3SbH2, C2H5SbH2, and n-C4H9SbH2 with organosilicon chlorides or HCl produce a pale green macromolecular species with a metallic sheen analyzing as (RSb)x while the same stibines with iodine-containing reagents, I2, ICl, CI4, and (CH3)2AsI, produce a purple-black species, (RSbI0.4)x. With CH3AsCl2, the stibines yield only the all-arsenic macromolecule (CH3As)x and RSbCl2. No evidence for the formation of cyclooligomers of antimony is found. © 1979, American Chemical Society. All rights reserved.

引用

页码：543 / 545

页数：3

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