HIGHLY CROWDED TRANS-OLEFIN - MOLECULAR-STRUCTURE OF TRANS-1,2-BIS(MESO-[NICKEL(II)OCTAETHYLPORPHYRINYL])ETHENE

被引：30

作者：

KITAGAWA, R

KAI, Y

PONOMAREV, GV

SUGIURA, K

BOROVKOV, VV

KANEDA, T

SAKATA, Y

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

[2] RUSSIAN MINIST HLTH, INST BIOPHYS, MOSCOW 123182, RUSSIA

[3] RUSSIAN MINIST HLTH, INST BIOPHYS, MOSCOW 123182, RUSSIA

[4] OSAKA UNIV, INST SCI & IND RES, IBARAKI, OSAKA 567, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 06期

关键词：

D O I：

10.1246/cl.1993.1071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-Ray analysis of trans-1,2-bis{meso-[nickel(II)octaethylporphyrinyl]}ethene has revealed that the compound has nonplanar structure and the nickel-coordination planes of porphyrin rings are close to perpendicular (72.5-degrees) to the plane of the central double bond. Both porphyrin rings have saddle-shaped structure due to the steric repulsion between ethyl substituents.

引用

页码：1071 / 1074

页数：4

共 14 条

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