PRESSURE AND TEMPERATURE-DEPENDENCE OF THE STRUCTURAL-PROPERTIES OF THE MOLECULAR SEMICONDUCTING SALT - ALPHA'-(BEDT-TTF)(2)AG(CN)(2)

被引：8

作者：

CHASSEAU, D

GUIONNEAU, P

RAHAL, M

BRAVIC, G

GAULTIER, J

DUCASSE, L

KURMOO, M

DAY, P

机构：

[1] UNIV BORDEAUX 1, PHYSICOCHIM THEOR LAB, CNRS, URA 503, F-33405 TALENCE, FRANCE

[2] UCL ROYAL INST GREAT BRITAIN, LONDON W1X 4BS, ENGLAND

来源：

SYNTHETIC METALS | 1995年 / 70卷 / 1-3期

关键词：

Evolution - Monoclinic system - Pressure dependence - Semiconducting phases - Semiconducting salts - Superstructures - Temperature dependence;

D O I：

10.1016/0379-6779(94)02712-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The temperature and pressure dependence of the electrical conductivity of the alpha'-(BEDT-TTF)(2)Ag(CN)(2) salt shows a transition between two semiconducting phases at a critical temperature depending on pressure. This transition is crystallographically characterized by the appearance of a superstructure corresponding to the doubling of the b parameter. We present and discuss here the parameters evolution at decreasing temperature and increasing pressure and the structural evolution under constraints.

引用

页码：945 / 946

页数：2