ELECTRONIC TRANSITION IN DODEKAHEDRAL CRYSTAL FIELD .I. CYANOCOMPLEXES OF MOLYBDENUM

被引：18

作者：

BASU, M

BASU, S

机构：

[1] Department of Pure Chemistry, University College of Science, Calcutta

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1968年 / 30卷 / 02期

关键词：

D O I：

10.1016/0022-1902(68)80473-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electronic spectra have been observed in the visible region for three 8-co-ordinated molybdenum cyanides containing one, two or three d-electrons. If the observed transitions are interpreted in terms of a dodekahedral crystal field, the dodekahedral Dq values come out in the order M05+(6214 cm-1) > M04+(5312 cm-1) > M03+(5728 cm-1). For M04+ one crystal field band has been found to show vibrational structure which could be represented in terms of two fundamental vibrations, 482 cm-1 and 346 cm-1. A tentative assignment has been made. © 1968.

引用

页码：467 / &