ESR STUDY OF SOME GROUP-IVB RADICAL ADDUCTS WITH AROMATIC KETONES

被引：17

作者：

ALBERTI, A ^{[1
]}

HUDSON, A ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)86707-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hyperfine coupling constants are reported for the paramagnetic adducts of silyl, germyl and stannyl radicals with five aromatic ketones. The spin distribution in these systems is compared with the H atom adducts and analogous hydrocarbon radicals. The large 117Sn and 119Sn satellite splittings observed in the stannyl adducts indicate that these radicals exist in a conformation with the O Sn bond orthogonal to the π-system. The ESR spectrum of the previously unknown anthronyl radical has been recorded and analysed. © 1979.

引用

页码：219 / 225

页数：7

共 19 条

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