FORMATION OF A TRICYCLIC [2.2]PARACYCLOPHANE DERIVATIVE IN THE LOW-TEMPERATURE PHOTOREACTION OF AN UNSYMMETRIC DIOLEFIN CRYSTAL

被引：8

作者：

CHUNG, CM

NAKAMURA, F

HASHIMOTO, Y

HASEGAWA, M

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 05期

关键词：

D O I：

10.1246/cl.1991.779

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Propyl alpha-cyano-4-[2-(4-pyrimidyl)ethenyl]cinnamate crystal afforded a tricyclic [2.2]paracyclophane derivative upon photoirradiation at low temperatures even though it gave a monocyclic dimer and oligomers at room temperature. This result is very significant in understanding of photochemical behavior of organic crystals at low temperature and in development of a new synthetic route of highly strained [2.2]paracyclophane derivative.

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页码：779 / 782

页数：4

相关论文

共 9 条

[1] KINETIC FEATURES OF TOPOCHEMICAL PROCESSES OF OLEFIN CRYSTALS [J].

HASEGAWA, M ;

SHIBA, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (09) :1490-1492

[2] TOPOCHEMICAL PHOTOPOLYMERIZATION OF DIOLEFIN CRYSTALS [J].

HASEGAWA, M .

PURE AND APPLIED CHEMISTRY, 1986, 58 (09) :1179-1188

[3] ASYMMETRIC-SYNTHESIS THROUGH THE TOPOCHEMICAL REACTION IN A CHIRAL CRYSTAL OF A PROCHIRAL DIOLEFIN MOLECULE HAVING A CISOID MOLECULAR-STRUCTURE AND AMPLIFICATION OF ASYMMETRY BY A SEEDING PROCEDURE [J].

HASEGAWA, M ;

CHUNG, CM ;

MURO, N ;

MAEKAWA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5676-5677

[4] QUANTITATIVE FORMATION OF A [2.2]PARACYCLOPHANE DERIVATIVE VIA TOPOCHEMICAL PHOTOREACTION OF CRYSTAL COMPLEX OF ETHYL AND PROPYL ALPHA-CYANO-4-[2-(4-PYRIDYL)ETHENYL]CINNAMATES [J].

HASEGAWA, M ;

MAEKAWA, Y ;

KATO, S ;

SAIGO, K .

CHEMISTRY LETTERS, 1987, (05) :907-910

[5] TOPOCHEMICAL PHOTOPOLYMERIZATION AND PHOTOCOPOLYMERIZATION OF THE CRYSTALS OF UNSYMMETRICALLY SUBSTITUTED DIOLEFIN COMPOUNDS HAVING PYRIMIDINE RING [J].

HASEGAWA, M ;

ENDO, Y ;

AOYAMA, M ;

SAIGO, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (05) :1556-1560

[6]

HASEGAWA M, 1989, PHOTOPOLYMERIZATION, P187

[7]

MAEKAWA Y, 1990, 59TH NAT M CHEM SOC

[8]

MAEKAWA Y, IN PRESS J AM CHEM S

[9] TOPOCHEMISTRY .3. CRYSTAL CHEMISTRY OF SOME TRANS-CINNAMIC ACIDS [J].

SCHMIDT, GMJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JUN) :2014-&