UNUSUAL ADDITION BY THE THIOL-ENE PHOTOPOLYMERIZATION

被引：3

作者：

KLEMM, E

BEIL, U

机构：

[1] Institut für Organische Chemie und Makromolekulare Chemie, Friedrich-Schiller-Universität Jena, Jena, O-6900

来源：

POLYMER BULLETIN | 1992年 / 28卷 / 06期

关键词：

D O I：

10.1007/BF00295968

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The photoaddition of aromatic dithiols (1) onto aliphatic alkenes (2a - 2c) yielding polysulfides is studied. Polysulfides having anti-Markownikow and Markownikow moieties in the main chain are obtained by the reaction of dithiols (1) with ethyleneglycoldivinylether (2a). The unusual Markownikow orientation is explained on the basis of a radical cation intermediate.

引用

页码：653 / 656

页数：4

共 6 条

[1] BEIL U, 1991, THESIS JENA, P63
[2] ADDITION POLYMERIZATION OF ALIPHATIC DITHIOLS WITH DIENE MONOMERS
KLEMM, E
SENSFUSS, S
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1991, A28 (09): : 875 - 883
[3] LENZ RW, 1967, ORGANIC CHEM SYNTHET, P196
[4] POLYARYLENE-ALKYLENE SULFIDES
MARVEL, CS
CAESAR, PD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (03) : 1097 - 1099
[5] Information on unsaturated compounds II The addition of mercaptan to unsaturated hydrocarbon
Posner, T
[J]. BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1905, 38 : 646 - 657
[6] VOLKEL T, 1990, THESIS BAYREUTH, P91

← 1 →