STABILIZATION OF NICKEL(III)-1,8-DIMETHYL-1,3,6,8,10,13-HEXAAZACYCLOTETRADECANE BY AXIAL BINDING OF ANIONS IN NEUTRAL AQUEOUS-SOLUTIONS

被引：23

作者：

ZILBERMANN, I

MESHULAM, A

COHEN, H

MEYERSTEIN, D

机构：

[1] BEN GURION UNIV NEGEV,NUCL RES CTR NEGEV,IL-84105 BEER SHEVA,ISRAEL

[2] BEN GURION UNIV NEGEV,DEPT CHEM,IL-84105 BEER SHEVA,ISRAEL

来源：

INORGANICA CHIMICA ACTA | 1993年 / 206卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)82857-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title tervalent nickel complex, Ni(III)L5aq, is stabilized in neutral and slightly alkaline aqueous solutions in the presence of stabilizing anionic ligands via the formation of Ni(III)L5X2 complexes, where X=F-, SO42-, HPO42-, HCO2-, C6H5CO2-, CH3CO2- and (CH3)3CCO2-. These complexes can be used as new powerful single electron oxidizing reagents in this medium. Some of the properties of the Ni(III)L5X2 complexes are described and discussed.

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页码：127 / 130

页数：4

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