RADIATION-INDUCED IONIC GRAFTING OF ETHYL VINYL ETHER TO POLYPROPYLENE FILM

被引：9

作者：

KABANOV, VY

KUBOTA, H

STANNETT, V

机构：

[1] Department of Chemical Engineering, North Carolina State University, Raleigh

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1979年 / A13卷 / 06期

关键词：

D O I：

10.1080/00222337908056691

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radiation-induced grafting of ethyl vinyl ether to polypropylene film in bulk has been investigated under super-dry conditions. The per cent grafting increased linearly with increasing dose without an induction period. The grafting did not take place in the presence of traces of water, indicating that the grafting proceeds by an ionic mechanism. The dose-rate dependence of the rate of grafting was found to be 0.25. The grafting was also examined in n-pentane and neopentane solutions. Although the per cent grafting in the solution system was lower than that in the bulk system, n-pentane was found to increase the grafting efficiency. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：807 / 814

页数：8

共 7 条

[1]

ALLEN AD, 1978, NSRDSNBS57

[2]

CHAPIRO A, 1976, J POLYM SCI S, V56, P431

[3] KINETIC STUDIES OF FREE CATIONIC POLYMERIZATION OF ETHYL VINYL ETHER AND ISOBUTYL VINYL ETHER INITIATED BY TRIPHENYLMETHYL HEXACHLOROANTIMONATE [J].