SYNTHESIS AND CHARACTERIZATION OF FERROCENYL AND BIS(FERROCENYL) ALKYNES AND POLYYNES - CRYSTAL-STRUCTURE OF 1,4-BIS(FERROCENYL)BUTADIYNE AND 3RD-ORDER NONLINEAR-OPTICAL PROPERTIES OF 1,8-BIS(FERROCENYL)OCTATETRAYNE

被引：151

作者：

YUAN, Z ^{[1
]}

STRINGER, G ^{[1
]}

JOBE, IR ^{[1
]}

KRELLER, D ^{[1
]}

SCOTT, K ^{[1
]}

KOCH, L ^{[1
]}

TAYLOR, NJ ^{[1
]}

MARDER, TB ^{[1
]}

机构：

[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 452卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83181-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple method, utilizing a coupling reaction between ethynylferrocene and cis-1,2-dichloroethylene catalyzed by Pd(PPh3)4/CuI or Pd(PPh3)2Cl2/CuI, for the stepwise preparation of ferrocenylbutadiyne is described. Complete H-1 and C-13 NMR characterization of (eta-C5H5)Fe(eta-C5H4)(C=C)(n)H (n = 1, 2), (eta-C5H5)Fe(eta-C5H4)(C+C)n(eta-C5H4)Fe(eta-C5H5) (n = 2, 4) and Z-(eta-C5H5) Fe(eta-C5H4)C=C-CH=CHCl, an X-ray crystal structure study of 1,4-bis(ferrocenyl)butadiyne, and the third order nonlinear optical behavior (second molecular hyperpolarizability, gamma) of 1,8-bis(ferrocenyl) octatetrayne are reported.

引用

页码：115 / 120

页数：6

共 34 条

[1] RATES AND MECHANISM OF THE REVERSIBLE OXIDATIVE ADDITION OF (Z)-1,2-DICHLOROETHYLENE AND (E)-1,2-DICHLOROETHYLENE TO LOW-LIGATED ZERO-VALENT PALLADIUM [J].

AMATORE, C ;

AZZABI, M ;

JUTAND, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) :1670-1677

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[3] DOES MARCUS HUSH THEORY REALLY WORK - OPTICAL STUDIES OF INTERVALENCE TRANSFER IN ACETYLENE-BRIDGED BIFERROCENE MONOCATION AT INFINITE DILUTION AND AT FINITE IONIC STRENGTHS [J].

BLACKBOURN, RL ;

HUPP, JT .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (05) :1788-1793

[4] SYNTHESIS OF BIS(3,4-DIMETHYLCYCLOPENTADIENYL)ACETYLENE AND BRIDGED METALLOCENES (ETA-5-C5ME5)M[ETA-5-C5H2ME2)CC(ETA-5-C5H2ME2)]M(ETA-5-C5ME5) (M = FE, NI) DERIVED THEREFROM [J].

BUNEL, EE ;

VALLE, L ;

JONES, NL ;

CARROLL, PJ ;

GONZALEZ, M ;

MUNOZ, N ;

MANRIQUEZ, JM .

ORGANOMETALLICS, 1988, 7 (03) :789-791

[5] MOLECULAR 2ND-ORDER OPTICAL NONLINEARITIES OF METALLOCENES [J].

CALABRESE, JC ;

CHENG, LT ;

GREEN, JC ;

MARDER, SR ;

TAM, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) :7227-7232

[6] EXPERIMENTAL INVESTIGATIONS OF ORGANIC MOLECULAR NONLINEAR OPTICAL POLARIZABILITIES .1. METHODS AND RESULTS ON BENZENE AND STILBENE DERIVATIVES [J].

CHENG, LT ;

TAM, W ;

STEVENSON, SH ;

MEREDITH, GR ;

RIKKEN, G ;

MARDER, SR .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (26) :10631-10643

[7] QUADRATIC HYPERPOLARIZABILITIES OF SOME ORGANOMETALLIC COMPOUNDS [J].

CHENG, LT ;

TAM, W ;

MEREDITH, GR ;

MARDER, SR .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 189 :137-153

[8]

COLES BF, 1975, J CHEM SOC DA, P443

[9] UBER FERROCEN-ACETYLENE, 4.MITT. - DARSTELLUNG UND LICHTABSORPTION VON FERROCENYL-THIOPHENEN UND DERIVATEN DES FERROCENYL-ACETYLENS [J].

EGGER, H ;

SCHLOGL, K .

MONATSHEFTE FUR CHEMIE UND VERWANDTE TEILE ANDERER WISSENSCHAFTEN, 1964, 95 (06) :1750-&

[10] UNUSUAL STRUCTURAL DISTORTIONS INDUCED BY CHARGE-TRANSFER INTERACTIONS THROUGH CONJUGATED MOLECULES - CRYSTAL-STRUCTURES OF NH2C6H4(C=C)NC6H4NO2 (N = 0-3) [J].

GRAHAM, EM ;

MISKOWSKI, VM ;

PERRY, JW ;

COULTER, DR ;

STIEGMAN, AE ;

SCHAEFER, WP ;

MARSH, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (24) :8771-8779

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