A STUDY OF FLUORIDE COMPLEXES OF CADMIUM BY AC AND DC POLAROGRAPHY

被引：26

作者：

BOND, AM

机构：

[1] Department of Inorganic Chemistry, University of Melbourne, Parkville

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1969年 / 20卷 / 02期

关键词：

D O I：

10.1016/0368-1874(69)80067-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A.c. polarographic measurements on aqueous solutions containing cadmium and fluoride ions have shown the existence of the species, CdF+ and CdF2, with stability constants (at 30° and an ionic strength of I.o) of 5.8 and 4, respectively. Reproducibility studies of a.c. techniques as a means for measuring changes in half-wave potentials (upon which the polarographic method for the determination of stabilities is based) have shown that the results obtained from a.c. polarographic measurements should be more accurate than those obtained by conventional d.c. polarography. © 1969.

引用

页码：223 / &

共 13 条

[1]

BARD AJ, 1966, ELECTROANALYTICAL ED, V1, pCH1

[2] POLAROGRAPHY WITH ALTERNATING CURRENTS .2. AC POLAROGRAPHY OF CADMIUM, ZINC, LEAD, THALLIUM, INDIUM, BISMUTH, AND ANTIMONY [J].