THE EXPLOITATION OF NEW SYNTHETIC REACTIONS BY MEANS OF RARE-EARTH-METALS

被引：21

作者：

TAKAKI, K

FUJIWARA, Y

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Higashi-Hiroshima

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1990年 / 4卷 / 04期

关键词：

imines; organic synthesis by lanthanoids; umpolung of ketones; ytterbium;

D O I：

10.1002/aoc.590040402

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This review deals with lanthanoid mediated organic reactions investigated by the authors. The scope of the lanthanoid‐mediated reactions are discussed under the following topics: Reactions of Yb metal umpoled diaryl ketones with electrophiles; Reactions of Yb metal with imines; Reactions of Yb metal with CC multiple bonds; Reactions of Sm metal with nitroarenes; Reactions of Yb metal with α,β‐unsaturated carbonyl compounds; Reactions of a PhYbI σ‐complex; Reactions of LnCl3 as Friedel‐Crafts catalyst. Copyright © 1990 John Wiley & Sons Ltd.

引用

页码：297 / 310

页数：14

共 49 条

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