ACRYLONITRILE-SMECTITE COMPLEXES

被引：19

作者：

BERGAYA, F

KOOLI, F

机构：

来源：

CLAY MINERALS | 1991年 / 26卷 / 01期

关键词：

D O I：

10.1180/claymin.1991.026.1.04

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption of acrylonitrile (AN) monomer vapour in the interlamellar space of smectitcs exchanged with different cations (Na or Y or hexylammonium) was monitored and used to yield macromolecular layers. Polymerization in the presence or absence of a free-radical initiator was obtained by heating at 100-degrees-C for 72 h. Cyclization can already be obtained at this stage, and is completed by heating the polyacrylonitrile (PAN)-complexes at 220-degrees-C for 48 h.

引用

页码：33 / 41

页数：9

共 14 条

[1] ADSORPTION OF ALCOHOLS BY SMECTITES .4. MODELS [J].