DIASTEREOSELECTIVE ALLYLATION OF DELTA HYDROXY CARBONYL-COMPOUNDS BY ALLYLIC ALCOHOLS WITH PD-SNCL2

被引：13

作者：

TAKAHARA, JP

MASUYAMA, Y

KURUSU, Y

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 05期

关键词：

D O I：

10.1246/cl.1991.879

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allylation of omega-hydroxy carbonyl compounds by allylic alcohols with Pd-SnCl2 proceeded smoothly in neutral polar medium with high regio- and diastereocontrol via chelated bicyclic transition state.

引用

页码：879 / 882

页数：4

共 12 条

[1]

Anh N. T., 1980, TOP CURR CHEM, V88, P145

[2]

CHEREST M, 1968, TETRAHEDRON LETT, P2199

[3]

KECK GE, 1984, TETRAHEDRON LETT, V25, P265, DOI 10.1016/S0040-4039(00)99857-5

[4]

KOGA K, 1972, CHEM PHARM BULL, V20, P526

[5] ALLYLIC ALCOHOLS AS SYNTHONS OF ALLYLIC CARBANIONS - PALLADIUM-CATALYZED CARBONYL ALLYLATION BY ALLYLIC ALCOHOLS WITH SNCL2 [J].

MASUYAMA, Y ;

TAKAHARA, JP ;

KURUSU, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (13) :4473-4474

[6] PALLADIUM-CATALYZED CARBONYL ALLYLATION BY ALLYLIC ALCOHOLS WITH SNCL2 - A SOLVATION-CONTROLLED DIASTEREOSELECTION [J].

MASUYAMA, Y ;

TAKAHARA, JP ;

KURUSU, Y .

TETRAHEDRON LETTERS, 1989, 30 (26) :3437-3440

[7] PALLADIUM-CATALYZED CARBONYL ALLYLATION OF DIKETO COMPOUNDS BY ALLYLIC ALCOHOLS WITH SNCL2 [J].

MASUYAMA, Y ;

TSUNODA, T ;

KURUSU, Y .

CHEMISTRY LETTERS, 1989, (09) :1647-1650

[8]

Pereyre M., 1987, TIN ORGANIC SYNTHESI

[9]

Reetz M. T., 1986, ORGANOTITANIUM REAGE

[10] CHELATION OR NON-CHELATION CONTROL IN ADDITION-REACTIONS OF CHIRAL ALPHA-ALKOXY AND BETA-ALKOXY CARBONYL-COMPOUNDS [J].

REETZ, MT .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (08) :556-569

← 1 2 →