MICROSCOPIC THEORY OF ORIENTATIONAL DISORDER AND THE ORIENTATIONAL PHASE-TRANSITION IN SOLID C-60

被引：96

作者：

MICHEL, KH ^{[1
]}

COPLEY, JRD ^{[1
]}

NEUMANN, DA ^{[1
]}

机构：

[1] NATL INST STAND & TECHNOL,MAT SCI & ENGN LAB,GAITHERSBURG,MD 20899

来源：

PHYSICAL REVIEW LETTERS | 1992年 / 68卷 / 19期

关键词：

D O I：

10.1103/PhysRevLett.68.2929

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We have developed a microscopic theory which describes the orientational dynamics of C60 molecules in the face-centered-cubic phase of C60 fullerite. The molecular interaction potential and the crystal-field potential are formulated in terms of symmetry-adapted rotator functions. The phase transition to the Pa3BAR structure is driven by an active multipolar mode of T2g symmetry belonging to the l = 10 manifold. The Birman criterion is satisfied. The transition is found to be of first order.

引用

页码：2929 / 2932

页数：4

共 26 条

[1] SIMPLIFIED THEORY OF SYMMETRY CHANGE IN 2ND-ORDER PHASE TRANSITIONS - APPLICATION TO V3SI
BIRMAN, JL
[J]. PHYSICAL REVIEW LETTERS, 1966, 17 (24) : 1216 - &
[2] Bradley C., 2009, MATH THEORY SYMMETRY
[3] MOLECULAR-DYNAMICS INVESTIGATION OF ORIENTATIONAL FREEZING IN SOLID C-60
CHENG, A
KLEIN, ML
[J]. PHYSICAL REVIEW B, 1992, 45 (04): : 1889 - 1895
[4] MOLECULAR-DYNAMICS SIMULATIONS OF SOLID BUCKMINSTERFULLERENES
CHENG, AL
KLEIN, ML
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (18) : 6750 - 6751
[5] CRYSTAL-STRUCTURE AND BONDING OF ORDERED C60
DAVID, WIF
IBBERSON, RM
MATTHEWMAN, JC
PRASSIDES, K
DENNIS, TJS
HARE, JP
KROTO, HW
TAYLOR, R
WALTON, DRM
[J]. NATURE, 1991, 353 (6340) : 147 - 149
[6] DWORKIN A, 1991, R ACAD SCI PARIS 2, V312, P979
[7] FLEMING RM, 1991, MATER RES SOC SYMP P, V206, P691
[8] GUO YJ, 1991, NATURE, V351, P464, DOI 10.1038/351464a0
[9] HARRIS AB, IN PRESS
[10] ORIENTATIONAL ORDERING TRANSITION IN SOLID C60
HEINEY, PA
FISCHER, JE
MCGHIE, AR
ROMANOW, WJ
DENENSTEIN, AM
MCCAULEY, JP
SMITH, AB
COX, DE
[J]. PHYSICAL REVIEW LETTERS, 1991, 66 (22) : 2911 - 2914

← 1 2 3 →