ON THE MODE OF BAKERS-YEAST REDUCTION OF METHYL-SUBSTITUTED ARYLALKYL-GAMMA AND DELTA-KETO ACIDS - SYNTHESIS OF CIS-(+)-ROSE OXIDE

被引：14

作者：

FRONZA, G

FUGANTI, C

GRASSELLI, P

TERRENI, M

机构：

[1] Dipartimento di Chimica del Politecnico, Centro CNR per la Chimica delle Sostanze Organiche Naturali

来源：

TETRAHEDRON | 1992年 / 48卷 / 35期

关键词：

D O I：

10.1016/S0040-4020(01)88272-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Baker's yeast reduction of methyl substituted gamma-and delta-keto acids 1-6 proceeds in a mode depending upon subtle substrate structural modifications; it affords gamma-lactones of modest ee and de values and highly functionalized, enantiomerically pure delta-lactones, such as 13 from which cis-(+)-rose oxide 23a has been prepared.

引用

收藏

页码：7363 / 7372

页数：10

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