TEMPERATURE-DEPENDENCE OF NONRADIATIVE DECAY

被引：102

作者：

CLAUDE, JP ^{[1
]}

MEYER, TJ ^{[1
]}

机构：

[1] UNIV N CAROLINA, DEPT CHEM, CHAPEL HILL, NC 27599 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 01期

关键词：

D O I：

10.1021/j100001a010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The temperature dependences of nonradiative decay for the metal-to-ligand charge transfer excited states of [Re(bpy)(Co)(3)(4-Etpy)](PF6) and [Os(bpy)(2)(CO)(Py)(PF6)(2) (bpy = 2,2'-bipyridine; 4-Etpy 4-ethylpyridine; py pyridine) follow the behavior predicted by the energy gap law. The variations with temperature can be calculated to within a factor of 2-3 by using parameters derived from a Frank-Condon analysis of emission spectral profiles.

引用

页码：51 / 54

页数：4

共 42 条

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