ENANTIOPURE HYDROXYLACTONES FROM L-ASCORBIC AND D-ISOASCORBIC ACIDS .2. SYNTHESIS OF (-)-(5R, 6S)-6-ACETOXY-5-HEXADECANOLIDE AND ITS DIASTEREOMERS

被引：13

作者：

GRAVIERPELLETIER, C

LEMERRER, Y

DEPEZAY, JC

机构：

[1] Université René Descartes, Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques, associé au CNRS, 75270 Paris Cedex 06, 45, rue des Saints Pères

来源：

TETRAHEDRON | 1995年 / 51卷 / 06期

关键词：

L-ASCORBIC ACID; D-ISOASCORBIC ACID; 6-HYDROXY-DELTA-VALEROLACTONES; MOSQUITO OVIPOSITION ATTRACTANT PHEROMONE; BIS-EPOXIDE; MITSUNOBU REACTION;

D O I：

10.1016/0040-4020(94)01033-V

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Strategies to enantiopure 6-hydroxy-delta-valerolactones, through bis-epoxide formal equivalents issued from L-ascorbic and D-isoascorbic acids, are studied. The approaches notably involve Mitsunobu reaction on diols or triols and opening of the resulting epoxides.

引用

页码：1663 / 1674

页数：12

共 19 条

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