EFFECT OF THE WATER OF CRYSTALLIZATION ON THE MOSSBAUER-SPECTRA OF HEXACYANOFERRATES (II AND III)

被引：36

作者：

REGUERA, E

FERNANDEZBERTRAN, J

机构：

[1] National Center for Scientific Research, Havana

来源：

HYPERFINE INTERACTIONS | 1994年 / 88卷 / 1-3期

关键词：

D O I：

10.1007/BF02068701

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Mossbauer spectra were recorded on hydrated, dehydrated and rehydrated hexacyanoferrate (II and III) samples including alkaline, alkaline-earth, transition metal and rare-earth salts. The location of the water molecules around the complex hexacyanoferrate anion has a decisive role on the quadrupole splitting of the low-spin Fe(III) cation.

引用

页码：49 / 58

页数：10

共 17 条

[1]

AYRES JB, 1971, J INORG NUCL CHEM, V33, P721

[2] CRYSTAL-STRUCTURE OF LAFE(CN)6.5H2O [J].

BAILEY, WE ;

WILLIAMS, RJ ;

MILLIGAN, WO .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, B 29 (JUL15) :1365-1368

[3]

GREEN AF, 1963, J INORG NUCL CHEM, V25, P1471

[4]

GREENWOOD NN, 1971, MOSSBAUER SPECTROSCO, P91

[5]

HRINKIEWICZ AZ, 1970, PHYS STATUS SOLIDI, V38, pK111

[6] RARE-EARTH FERRICYANIDES AND CHROMICYANIDES LNT(CN)6.NH2O [J].

HULLIGER, F ;

LANDOLT, M ;

VETSCH, H .

JOURNAL OF SOLID STATE CHEMISTRY, 1976, 18 (03) :283-291

[7]

Ludi A., 1973, INORGANIC CHEM INORG, P1, DOI [10.1007/bfb0016869, DOI 10.1007/BFB0016869]

[8] A STRUCTURAL INVESTIGATION OF PRASEODYMIUM POTASSIUM HEXACYANOFERRATE (II) TETRAHYDRATE, PRKFE(CN)6.4H2O [J].

MULLICA, DF ;

SAPPENFIELD, EL ;

PERKINS, HO .

JOURNAL OF SOLID STATE CHEMISTRY, 1988, 73 (01) :65-70

[9]

PETTER W, 1992, EUR J SOL STATE INOR, V29, P65

[10]

PETTER W, 1992, EUR J SOLID STATE CH, V29, P5

← 1 2 →