CRYSTAL-STRUCTURES OF THE SOLVATES TRANS-[RHCL2(MEOH)(C6H3-2,6-(CH(2)PCY(2))(2))].0.41CH(2)CL(2) AND TRANS-[RHCL2(ETOH)(C6H3-2,6-(CH(2)PCY(2))2)].H2O - FACTORS INFLUENCING THE REACTIONS OF C6H4-1,3-(CH(2)PR(2))(2) WITH RHCL3

被引：16

作者：

CROSS, RJ

KENNEDY, AR

MANOJLOVICMUIR, L

MUIR, KW

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

RHODIUM; TERDENTATE LIGANDS; CRYSTAL STRUCTURE; ORTHOMETALLATION;

D O I：

10.1016/0022-328X(94)05361-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The terdentate ligands C6H3-2,6-(CH(2)PCy(2))(2) (PCP: Cy = cyclohexyl) in the octahedral solvento complexes trans-[RhCl2(MeOH)(PCP)] and trans-[RhCl2(EtOH)(PCP)] adopt conformations which minimise the interactions between the sterically demanding Cy groups and the trans chlorides. Comparison of these structures with those of related molecules, including square-pyramidal and square-planar species, suggests an explanation for the different structural types obtained as products from reactions of RhCl3.3H(2)O and various ligands C6H4-1,3-(CH(2)ER(2))(2) with E = N or P.

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页码：243 / 249

页数：7

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