FACILE ENANTIOSELECTIVE SYNTHESIS OF 2 NEW BICYCLIC CHIRAL TEMPLATES

被引：7

作者：

BELFIELD, KD

SEO, J

机构：

[1] Department of Chemistry, University of Detroit Mercy, Detroit, MI 48219

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 04期

关键词：

D O I：

10.1080/00397919508011379

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active bicyclic dienes, 4 and 5 have been enantioselectively prepared in three and four steps, respectively. Mixtures of predominantly either the R or S enantiomer were obtained via an asymmetric alkylation of a chiral enamine.

引用

页码：461 / 466

页数：6

共 4 条

[1] DIRECT DETERMINATION OF ENANTIOMERIC EXCESS OF CARBOCYCLIC ESTERS BY CHIRAL CAPILLARY GAS-CHROMATOGRAPHY [J].

BELFIELD, KD ;

HOFMEISTER, TS ;

SEO, J .

JOURNAL OF CHROMATOGRAPHY, 1993, 648 (02) :497-500

[2] SYNTHESIS OF OPTICALLY-ACTIVE MICHAEL ADDUCTS VIA CHIRAL ENAMINES [J].

BRUNNER, H ;

KRAUS, J ;

LAUTENSCHLAGER, HJ .

MONATSHEFTE FUR CHEMIE, 1988, 119 (10) :1161-1167

[3] SESQUITERPENE LACTONES - TOTAL SYNTHESIS OF (+/-)-VERNOLEPIN AND (+ [J].

GRIECO, PA ;

NISHIZAWA, M ;

OGURI, T ;

BURKE, SD ;

MARINOVIC, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (17) :5773-5780

[4] FACILE SYNTHESIS OF THE VERSATILE SYNTHON 1-METHYLENE-5,5,8A-TRIMETHYL-2-OXODECAHYDRONAPHTHALENE [J].

NAIR, MS ;

ANILKUMAR, AT .

SYNTHETIC COMMUNICATIONS, 1994, 24 (08) :1085-1090

← 1 →