MASS SPECTRA OF SUBSTITUTED THIOGLYCOLLIC ACIDS AND ESTERS . SKELETAL REARRANGEMENT UPON ELECTRON-IMPACT

被引：14

作者：

BOWIE, JH

MADSEN, JO

LAWESSON, SO

COOKS, RG

机构：

[1] Department of Organic Chemistry, University of Adelaide, Adelaide, South Australia

[2] Department of Organic Chemistry, Aarhus University, Århus

[3] Department of Chemistry, Kansas State University, Manhattan, Kansas

来源：

ORGANIC MASS SPECTROMETRY | 1969年 / 2卷 / 04期

关键词：

D O I：

10.1002/oms.1210020409

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mass spectra of thioglycollic acids and esters are reported and discussed. The spectra of compounds of the type X·CH(Y)·S·CH2·COOR(X > Y) contain skeletal rearrangement fragments with the composition R·Y·C2H3SO+. Ions produced by simple cleavage processes may be usefully correlated with structure. Copyright © 1969 John Wiley & Sons, Ltd.

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页码：413 / &

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