FLUOROCYCLOPROPANES .2. SYNTHESIS PROPERTIES AND REACTIONS OF PERFLUOROCYCLOPROPENE

被引：85

作者：

SARGEANT, PB

KRESPAN, CG

机构：

[1] Central Research Department, Experimental Station, E. I. du Pont de Nemours and Company, Wilmington

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 02期

关键词：

D O I：

10.1021/ja01030a035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perfluorocyclopropene has been prepared by the dehydrohalogenation of pentafluorocyclopropane and 1-chloro-1,2,2,3-tetrafluorocyclopropane and most conveniently by the dehalogenation of 1,2-dichloro-1,2,3,3-tetra-fluorocyclopropane. Perfluorocyclopropene is a flammable, explosive gas. It is surprisingly stable to many conditions, but reacts with nucleophiles, water, and antimony pentafiuoride. A Diels-Alder reaction occurs with 1,3-dienes, and a 1,2-cycloaddition reaction was observed with tetrafluoroethylene. Perfluorocyclopropene also undergoes free-radical copolymerization with a variety of unsaturated comonomers. © 1969, American Chemical Society. All rights reserved.

引用

页码：415 / &

共 19 条

[1]

Banks RE., 1964, FLUOROCARBONS THEIR

[2] REVIEW OF CHEMISTRY OF CYCLOPROPENE COMPOUNDS [J].