CHEMI-LUMINESCENCE FROM OXIDATION OF POLYPROPYLENE - SOME COMMENTS ON A KINETIC APPROACH

被引:32
作者
BILLINGHAM, NC [1 ]
GEORGE, GA [1 ]
机构
[1] UNIV QUEENSLAND,DEPT CHEM,ST LUCIA,QLD 4067,AUSTRALIA
关键词
D O I
10.1002/polb.1990.090280301
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We present a detailed criticism of the kinetic approach to the analysis of data obtained from measurements of the very weak chemiluminescence accompanying the oxidation of polypropylene. It is shown that a kinetic model proposed by other workers is based upon invalid assumptions, leads to kinetic parameters which are not sensible, and requires measurement of the properties which it claims to predict. Copyright © 1990 John Wiley & Sons, Inc.
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页码:257 / 265
页数:9
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