PHOTO-DISSOCIATION OF NA+2 IN NA2 MULTI-PHOTON ABSORPTION

被引:19
作者
NITZ, DE [1 ]
HOGAN, PB [1 ]
SCHEARER, LD [1 ]
SMITH, SJ [1 ]
机构
[1] NBS, BOULDER, CO 80309 USA
关键词
D O I
10.1088/0022-3700/12/3/007
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Resonant two-photon ionisation of Na2 and subsequent third-photon dissociation of Na2+ has been studied with the use of a pulsed dye laser. Expressions for the time- and intensity-dependent populations of Na2+ and Na+ are derived and fit to observed ion signal variations with laser intensity. This analysis yields the cross section for photodissociation of the 2 Sigma g state of Na2+. The dissociation energy of this state is determined from the time-of-flight spectrum of Na2+ photofragments.
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页码:L103 / L108
页数:6
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