INFLUENCE OF ALCOHOLS IN REDOX CATALYZED TELOMERIZATION OF CHLOROTRIFLUOROETHYLENE

被引：5

作者：

BOUTEVIN, B

DOHEIM, M

PIETRASANTA, Y

RIGAL, G

机构：

[1] Laboratoire de Chimie Appliquée Ecole Nationale Supérieure de Chimie de Montpellier, 34075 Montpellier Cédex, 8, rue Ecole Normale

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1979年 / 14卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)82990-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The influence of alcohols, particularly of methanol and isopropanol has been studied in Redox catalyzed telomerization of trifluorochloroethylene and carbon tetrachloride. The nature of the by-products strongly favours participation of these alcohols during the transfer step. Results support formation of a reagent-metal complex during the course of the reaction. The latter does not follow as in the classical free radical telomerization. © 1979.

引用

页码：29 / 43

页数：15

共 18 条

[1] CHLORINE-ACTIVATION BY REDOX-TRANSFER .3. ABNORMAL ADDITION OF CHLOROFORM TO OLEFINS
ASSCHER, M
VOFSI, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (AUG): : 3921 - &
[2] CHLORINE ACTIVATION BY REDOX TRANSFER .2. ADDITION OF CARBON TETRACHLORIDE TO OLEFINS
ASSCHER, M
VOFSI, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (MAR): : 1887 - &
[3] BANKS RE, 1970, FLUOROCARBON THEIR D, P233
[4] BERRY KL, 1951, Patent No. 2559629
[5] BOUTEVIN B, 1976, EUR POLYM J, V12, P212
[6] BOUTEVIN B, 1975, THESIS MONTPELLIER
[7] CHUTNY B, CHEM ABSTR 104717Q, V84
[8] ENGLIN BA, 1968, IZV AKAD NAUK SSSR K, V6, P1251
[9] FREIDLINA RK, 1970, IZV AKAD NAUK SSSR K, V10, P2343
[10] FREIDLINA RK, 1969, DOKL AKAD NAUK SSSR, V188, P1073

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