FORMATION OF CYCLIC CARBOSILANES IN THE PYROLYSIS OF OCTAMETHYLTRISILANE

被引:7
作者
BORTOLIN, BN
DAVIDSON, IMT
LANCASTER, D
SIMPSON, T
WILD, DA
机构
[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND
[2] UNIV SUSSEX,DOW CORNING SUSSEX RES SCH MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND
关键词
D O I
10.1021/om00115a044
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Prominent products in the pyrolysis of the title compound are cyclic carbosilanes; evidence is presented that one of these is formed in a novel and potentially useful elimination reaction. © 1990, American Chemical Society. All rights reserved.
引用
收藏
页码:281 / 284
页数:4
相关论文
共 14 条
[1]   PULSED STIRRED-FLOW TECHNIQUE FOR GAS KINETICS [J].
BALDWIN, AC ;
DAVIDSON, IMT ;
HOWARD, AV .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1975, 71 (04) :972-979
[2]   RADICAL REARRANGEMENTS IN THE PYROLYSIS OF ALLYLDISILANES [J].
BARTON, TJ ;
JACOBI, SA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (27) :7979-7981
[3]   THERMOCHEMISTRY OF DISILANYL AND TRISILANYL RADICALS - OBSERVATIONS AND COMMENTS ON SILENE-TO-SILYLENE REARRANGEMENTS [J].
BARTON, TJ ;
BURNS, SA ;
BURNS, GT .
ORGANOMETALLICS, 1982, 1 (01) :210-212
[4]   DIRECT PHOTOLYSIS OF TETRAMETHYLSILANE IN THE GAS AND LIQUID-PHASES [J].
BASTIAN, E ;
POTZINGER, P ;
RITTER, A ;
SCHUCHMANN, HP ;
VONSONNTAG, C ;
WEDDLE, G .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1980, 84 (01) :56-62
[5]   KINETICS OF THERMAL ISOMERIZATION OF HEXAMETHYLDISILANE [J].
DAVIDSON, IM ;
EABORN, C ;
SIMMIE, JM .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1974, 70 (02) :249-252
[6]   MECHANISM OF THERMOLYSIS OF HEXAMETHYLDISILANE AND SILICON-SILICON BOND-DISSOCIATION ENERGY [J].
DAVIDSON, IM ;
HOWARD, AV .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1975, 71 (01) :69-77
[7]   KINETICS OF THE FORMATION OF SILYLENES FROM SOME DISILANES [J].
DAVIDSON, IMT ;
HUGHES, KJ ;
IJADIMAGHSOODI, S .
ORGANOMETALLICS, 1987, 6 (03) :639-643
[8]   KINETICS AND MECHANISM OF PYROLYSIS OF 1,1,3,3,4,4-HEXAMETHYL-1,3,4-TRISILACYCLOPENTANE [J].
DAVIDSON, IMT ;
LAWRENCE, FT ;
FRITZ, G ;
MATERN, E .
ORGANOMETALLICS, 1982, 1 (11) :1453-1455
[9]   A SIMPLE TECHNIQUE FOR GAS KINETIC-STUDIES IN ORGANO-SILICON CHEMISTRY [J].
DAVIDSON, IMT ;
EATON, G ;
HUGHES, KJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 347 (1-2) :17-25
[10]   THE MERCURY-PHOTOSENSITIZED DECOMPOSITION OF HEXAMETHYLDISILANE [J].
DAVIDSON, IMT ;
POTZINGER, P ;
REIMANN, B .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1982, 86 (01) :13-19