SOLUTION CHARACTERIZATION OF HIGH-MOLECULAR-WEIGHT POLYACRYLONITRILE OBTAINED BY PLASMA-INDUCED POLYMERIZATION

被引：15

作者：

SIMIONESCU, BC

IOAN, S

BERCEA, M

SIMIONESCU, CI

机构：

[1] INST POLYTECH GHEORGHE ASACHI,DEPT ORGAN & MACROMOLEC,R-6600 IASI,ROMANIA

[2] PETRU PONI INST MACROMOLEC CHEM,R-6600 IASI,ROMANIA

来源：

EUROPEAN POLYMER JOURNAL | 1991年 / 27卷 / 06期

关键词：

D O I：

10.1016/0014-3057(91)90182-N

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The behaviour of high molecular weight polyacrylonitrile, prepared by plasma-induced polymerization, in dilute solution in dimethylformamide was investigated by light scattering and viscometry. The dependence of the radius of gyration and of the second virial coefficient at 20-degrees-C and of the intrinsic viscosity at 15-50-degrees-C on the weight-average molecular weight of polymer was established. There is discussion of the possible appearance during the polymerization of branched structures, able to influence the mentioned dependencies.

引用

页码：553 / 556

页数：4

共 19 条

[1] THERMODYNAMIC AND CONFORMATIONAL PROPERTIES OF POLYSTYRENE .I. LIGHT-SCATTERING STUDIES ON DILUTE SOLUTIONS OF LINEAR POLYSTYRENES [J].