COPPER CATALYZED AMINOLYSIS OF BROMOALLENES AS A NEW EFFICIENT ROUTE TO PROPARGYLAMINES

被引：18

作者：

CAPORUSSO, AM

GERI, R

POLIZZI, C

LARDICCI, L

机构：

[1] Dipartimento di Chimica, Chimica Industriale dell'Università - Centro di Studio, CNR per le Macromolecole Stereordinate ed Otticamente Attive., 56126 Pisa

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 50期

关键词：

PROPARGYLAMINES; BROMOALLENES; AMINOLYSIS; REGIOSELECTIVITY; CU PROMOTED NUCLEOPHILIC SUBSTITUTION;

D O I：

10.1016/0040-4039(91)80138-V

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient procedure of general applicability for the synthesis of secondary and tertiary propargylamines by copper mediated aminolysis of 1-bromo-1,2-dienes is described.

引用

页码：7471 / 7472

页数：2

共 14 条

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[2] ACID-CATALYZED [3,3]-SIGMATROPIC REARRANGEMENTS OF N-PROPARGYLANILINES
BARMETTLER, P
HANSEN, HJ
[J]. HELVETICA CHIMICA ACTA, 1990, 73 (06) : 1515 - 1573
[3] REACTIONS OF 3-ALKYL-1-BROMOALLENES AND 3,3-DIALKYL-1-BROMOALLENES WITH ORGANOCUPRATES - EFFECTS OF THE NATURE OF THE CUPRATE REAGENT ON THE REGIOSELECTIVITY AND STEREOSELECTIVITY
CAPORUSSO, AM
POLIZZI, C
LARDICCI, L
[J]. TETRAHEDRON LETTERS, 1987, 28 (48) : 6073 - 6076
[4] CAPORUSSO AM, 1985, CHIM IND-MILAN, V67, P664
[5] CAPORUSSO AM, 1990, COMMUNICATION 0930
[6] DOUTHEAU AG, Patent No. 2576897
[7] DOUTHEAU AG, Patent No. 133407
[8] SYNTHESIS AND ABSOLUTE-CONFIGURATIONS OF HALOGENOALLENES
ELSEVIER, CJ
VERMEER, P
GEDANKEN, A
RUNGE, W
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (03) : 364 - 367
[9] FREY H, 1990, SYNTHESIS-STUTTGART, P931
[10] KAISER C, 1981, BURGERS MED CHEM

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