MASS-SPECTROMETRIC INVESTIGATIONS OF THE REACTIONS OF CL2 WITH CR2O3 AND CROCL AT HIGH-TEMPERATURES - THE HEAT OF FORMATION OF CROCL2,G

被引：15

作者：

PLIES, V

机构：

[1] Inst. f. Anorg. u. Analyt. Chemie, Justus-Liebig-Univ., Gießen, W-6300

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 602卷 / 11期

关键词：

CHROMIUM OXIDE CHLORIDES; GAS PHASE INVESTIGATION; MASS SPECTROMETRY;

D O I：

10.1002/zaac.19916020111

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The existence of CrOCl2,g could be proofed by mass-spectrometric investigations of the gaseous phase in the systems CrOCl/Cl2 and Cr2O3/Cl2 at temperatures between 900 and 1350 K. The molar heat of formation is determined by 2nd law calculations (DELTA-B)H298-degrees = -366.8 kJ.

引用

页码：97 / 104

页数：8

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