FORMATION AND ELECTRONIC ENERGIES OF THE MATRIX-ISOLATED HYDROGEN-NOBLE GAS MOLECULE

被引：10

作者：

WITTL, F ^{[1
]}

CREUZBURG, M ^{[1
]}

SCHRIEVER, R ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST EXPTL PHYS,W-1000 BERLIN 33,GERMANY

来源：

JOURNAL OF LUMINESCENCE | 1991年 / 48-9卷

关键词：

D O I：

10.1016/0022-2313(91)90204-9

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The photolysis of hydrogen-containing molecules in noble-gas (Ng) matrices results in hydrogen atoms caged in octahedral interstitial lattice sites. The excited states give rise to characteristic absorption bands and relax most probably into a Ng2H charge-transfer state. A simple model is proposed for calculating the potential of this state and also for the ground state. The results can be compared with new measurements of the photolytically induced fluorescence bands at 5 to 6 eV of H-doped solid noble gases.

引用

页码：611 / 615

页数：5

共 15 条

[1] DYNAMICS OF MOLECULAR REACTIONS IN SOLIDS - PHOTODISSOCIATION OF HI IN CRYSTALLINE XE [J].

ALIMI, R ;

GERBER, RB ;

APKARIAN, VA .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (01) :174-183

[2] LOW-TEMPERATURE PHOTOLYSIS OF HYDROCARBONS IN SOLID XENON - EVIDENCE FOR METASTABLE XENH [J].

CREUZBURG, M ;

KOCH, F ;

WITTL, F .

CHEMICAL PHYSICS LETTERS, 1989, 156 (04) :387-391

[3] HYDROGEN CENTERS IN SOLID NOBLE-GASES [J].

CREUZBURG, M ;

WITTL, F .

JOURNAL OF MOLECULAR STRUCTURE, 1990, 222 (1-2) :127-140

[4] COOPERATIVE PHOTOABSORPTION INDUCED CHARGE-TRANSFER REACTION DYNAMICS IN RARE-GAS SOLIDS .1. PHOTODYNAMICS OF LOCALIZED XENON CHLORIDE EXCIPLEXES [J].

FAJARDO, ME ;

APKARIAN, VA .

JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (10) :5660-5681

[5] EXCITONS IN RARE-GAS CRYSTALS [J].

FUGOL, IY .

ADVANCES IN PHYSICS, 1978, 27 (01) :1-87

[6] OBSERVATION OF XED AND XE2D IN NEON MATRIX [J].

GURTLER, P ;

KRAAS, M ;

TSCHENTSCHER, T .

EUROPHYSICS LETTERS, 1990, 11 (02) :115-120

[7]

KUNZ H, UNPUB PHYS REV B

[8]

RHODES CK, 1984, TOPICS APPLIED PHYSI, V30

[9] CAGE EFFECT FOR THE ABSTRACTION OF H FROM H2O IN AR MATRICES [J].

SCHRIEVER, R ;

CHERGUI, M ;

KUNZ, H ;

STEPANENKO, V ;

SCHWENTNER, N .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (07) :4128-4133

[10] A MODEL POTENTIAL FOR RYDBERG STATES OF ALKALI ATOMS IN RARE-GAS MATRICES [J].

SCHWENTNER, N ;

CHERGUI, M .

JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (06) :3458-3462

← 1 2 →